Live chat
Structure Search


   

 Home
 Order By
 Item
 Contact
 Us
 Static
 Link






002865

002865-1g



Silver tetrafluoroborate


CAS Number: 14104-20-2
   
Molecular Formula: AgBF4
   
Molecular Weight: 194.67
   
MDL Number: MFCD00003408


 Item #PriceQuantityAdd to Cart 
002865-1g
Regular Price: $19.00
Your Discounted Price: $0.00
In Stock USA
002865-5g
Regular Price: $26.00
Your Discounted Price: $0.00
In Stock USA
002865-25g
Regular Price: $98.00
Your Discounted Price: $0.00
In Stock USA
002865-100g
Regular Price: $300.00
Your Discounted Price: $0.00
In Stock USA



Purity:99%
Mp:70-73°
 
Pictograms:
Signal Word:Danger
Hazard Statements:H314, H318
Precautionary Statements:P280, P310, P305 + P351 + P338
UN#:UN3260
Packing Group:II
Hazard Class:8
RTECS:ED2875000
Risk Statements:34
Safety Statements:26-36/37/39-45
SDS: See MSDS
 
Limited Quantities:1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

Enter Lot No:


Submit
An inorganic compound encountered in inorganic and organometallic chemistry. Commonly used to replace halide anions or ligands with the weakly coordinating tetrafluoroborate anions.1 Applied in anion exchange reaction for synthesis of picoline-functionalized benzimidazolium salts N-alkyl-N'-picolylbenzimidazolium bromide and the dipicoline-functionalized benzimidazolium bromide,2 for oxidation of alcohols by persulfate,3 and as a silver-ion template for improved macrolatamization of a linear dipeptide.4 Also employed as a catalyst for cyclization of N-(propargylic)hydroxyl-lamines to afford the corresponding 4-isoxazolines,5 for stereoselective synthesis of benzylated catechin trimer,6 for synthsis of 1-aminoindolizines,7 for the ammonolysis-cyclization tandem reactions of various 2-alkynylbenzenamines with tetraalkylthiuram disulfides,8 and synthesis of polysubstituted pyrroles directly from alkynoates and amines.Acts as an excellent promoter for the activation of various glycosyl donors including glycosyl halides, trichloroacetimidates, and thioimidates.10

Reference

1.        Tetrahedron Lett. 197920, 3357. 
2.        Eur. J. Inorg. Chem. 2009, 1960.
3.        Synlett 2007, 1901.
4.        Synthesis 2004, 217.
5.        Chem. Lett. 201140, 440.
6.        Heterocycles 201183, 739.
7.        J. Comb. Chem. 201012, 696.
8.        Synlett 2010, 1345.
9.        Org. Lett. 201012, 312.
10.        Tetrahedron Lett. 200849, 1542.

<<  <    Page 1 of 1    >  >>