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021814

021814-5g



(1S)-(+)-10-Camphorsulfonic acid


CAS Number: 3144-16-9
   
Molecular Formula: C10H16O4S
   
Molecular Weight: 232.30
   
MDL Number: MFCD00064157


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021814-5g
Regular Price: $10.00
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021814-25g
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021814-100g
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021814-500g
Regular Price: $94.00
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021814-1kg
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Purity:99%
Mp:196-200°
 
Pictograms:
Signal Word:Danger
Hazard Statements:H314, H318
Precautionary Statements:P260, P280, P301 + P330 + P331, P302 + P352, P303 + P361 + P353, P304 + P340, P305 + P351 + P338, P310
UN#:UN2585
Packing Group:III
Hazard Class:8
RTECS:ED1550000
SDS: See MSDS
 
Limited Quantities:5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

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A relatively strong acid, used extensively in the optical resolution of amines e.g. Dutch resolution of racemic 4-hydroxy- and 4-fluorophenylglycine in the presence of phenylglycine.1 Has been used for generation of chiral polyaniline colloids via the electrohydrodynamic polymerization of aniline,2 preparation of optically active (camphorsulfonyl)oxaziridines,3 generation of enantiomerically pure (R,R)-(+)-2,3-diphenylpiperazine by resolution of the corresponding racemic mixture,4 synthesis of alpha-hydroxy and alpha-amino acids,5 catalyzing highly stereoselective synthesis of pseudoglycosides.6

1. Tetrahedron: Asymmetry 2000, 11, 1343.
2. Macromolecules 1998, 31, 6521.
3. J. Chem. Educ. 1999, 76, 1715.
4. J. Chem. Sci., Vol. 2008, 120, 175.
5. J. Org. Chem. 1998, 63, 5818.
6. Bioorg. Med. Chem. Lett. 2009, 19, 3093.

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