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024896

024896-25g



TFFH


CAS Number: 164298-23-1
   
Molecular Formula: C5H12F7N2P
   
Molecular Weight: 264.13
   
MDL Number: MFCD02684443


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024896-25g
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024896-100g
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024896-5g
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Purity:97%
Mp:104-108°
 
Pictograms:
Signal Word:Warning
Hazard Statements:H303, H313, H333
Precautionary Statements:P261, P305 + P351 + P338
MSDS: See MSDS
 

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A coupling reagent that proceeds via in situ conversion to an acid fluoride.1,2 A benign substitute for the corrosive cyanuric fluoride which suitable for the preparation of acyl fluorides even when unsaturated double bonds, hydroxyl groups, or aromatic rings are present.3,4 A convenient reagent for the preparation of isothiocyanates from the corresponding primary amines in the presence of carbon disulfide.5 A useful reagent for the conversion of carboxylic acids into esters, thioesters, anilides, hydrazides, acyl azides, the corresponding alcohols and hydroxamic acids.6,7,8

  1. J. Am. Chem. Soc. 1995, 117, 5401.
  2. Langmuir 2006,22, 6956.
  3. Synthesis 1973, 487.
  4. J. Org. Chem. 1996, 61, 6994. 
  5. Synth. Commun. 1998, 28, 1223.
  6. Synthesis 2004, 2485.
  7. ChemInform 2003, 34.
  8. ARKIVOC 2006 (xiii), 57.

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