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001461

001461-25g



Trifluoromethyl iodide


CAS Number: 2314-97-8
   
Molecular Formula: CF3I
   
Molecular Weight: 195.91
   
MDL Number: MFCD00001060

Cylinder Charge: Cylinder, valve, and tubing connection charge $70
Special Handling and Safety: Empty cylinder may be returned, at customer expense, within 1 year of purchase for disposal. No charge for disposal.

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001461-25g
Regular Price: $45.00
Your Discounted Price: $0.00
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001461-100g
Regular Price: $95.00
Your Discounted Price: $0.00
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001461-500g
Regular Price: $350.00
Your Discounted Price: $0.00
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Purity:99%
Bp:-22.5°
Mp:-110°
 
Pictograms:
Signal Word:Warning
Hazard Statements:H280, H341
Precautionary Statements:P201, P281, P403, P410
UN#:UN1956
Hazard Class:2.2
RTECS:PB6975000
Risk Statements:68
Safety Statements:36/37
SDS: See MSDS
 
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

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Reagent used for the trifluoromethylation of various compounds; e.g. using copper or zinc powder in the presence of various catalysts.1,2 Trifluoromethyl iodide has been used for nucleophilic trifluoromethylation of aldehydes and ketones  based on photoinduced reduction of trifluoromethyl iodide by tetrakis(dimethylamino)ethylene (TDAE).3 The reagent is also used for the rhodium-catalyzed -trifluoromethylation of α,β-unsaturated ketones,4 and enantioselective α -trifluoromethylation of aldehydes via photoredox organocatalysis using a readily available iridium photocatalyst and a commercial imidazolidinone catalyst.5 

1. Tetrahedron Lett. 2002, 43, 4317.
2. Tetrahedron Lett. 1993, 34, 2169.
3. Org. Lett. 2001, 3, 4271.
4. Int. J. Thermophys. 2000, 21, 393. 
5. J. Am. Chem. Soc.2009, 131, 10875.

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