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044626

044626-10ml



Deuterium oxide


CAS Number: 7789-20-0
   
Molecular Formula: D2O
   
Molecular Weight: 20.00
   
MDL Number: MFCD00044636


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Purity:99.9%
Bp:101°
Mp:3.8°
Density:1.12
 
Pictograms:
Signal Word:Warning
Hazard Statements:H302, H315, H319, H335
Precautionary Statements:P261, P301 + P312, P302 + P352, P304 + P340, P305 + P351 + P338
RTECS:ZC0230000
SDS: See MSDS
 

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Also called Heavy water. Widely applied in nuclear magnetic resonance, Fourier transform spectroscopy, neutron moderator, neutrino detector, metabolic rate testing in physiology/biology and organic chemistry. Used to prepare highly deuterated hydroxybenzoic acids,1 to deuterate N-benzyl-containing heterocyclic compounds using palladium/carbon-ethylenediamine complexes,2 to prepare deuterated compounds by substitution of carboxyl groups of carboxylic acids with deuterium by photochemical decarboxylation,3 to produce deuterated imidazole derivatives,4 and reduce enones into α,β-dideuterioketones by palladium catalysis.5 Also employed as a deuterium source for catalytic (transfer) deuterogenation,6 and isotopically labeling amino acid derivatives and heterocyclic compounds.7,8

Reference

1.        Org. Chem. 20118, 332.
2.        JP 2011016745 A 201101272011.
3.        Chem. Comm. 201046, 6177.
4.        JP 2009242343 A 200910222009.
5.        Chem. Comm. 2007, 1819.
6.        Dalton Trans. 2009, 6286.
7.        Synlet2008, 402.
8.        Tetrahedron 200662, 10954.

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