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044830

044830-1g



Difluoromethyltrimethylsilane

CAS Number: 65864-64-4
   
Molecular Formula: C4H10F2Si
   
Molecular Weight: 124.21
   
MDL Number: MFCD19381658


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044830-1g
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044830-5g
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044830-25g
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044830-100g
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Purity:97%
Bp:65-66°
 
Pictograms:
Signal Word:Danger
Hazard Statements:H225, H302, H315, H319, H333, H335
Precautionary Statements:P210, P232, P233, P280, P301 + P330 + P331, P302 + P352, P304 + P341, P305 + P351 + P338
UN#:UN1993
Packing Group:II
Hazard Class:3
Flash Point:-17°
SDS: See MSDS
 
Limited Quantities:1.0 L (0.3 gallon) (liquid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

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A versatile fluoromethylating reagent.  Efficiently difluoromethylates various aldehydes, ketones, and imines to give the corresponding products in good to excellent yields when using a proper Lewis base activator.

Reference
1. Org. Lett. 2011, 13, 5342.
2. J. Org. Chem. 2003, 68, 4457.

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