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011709

011709-250mg



(1S,2S)-(-)-1,2-Diphenylethylenediamine


CAS Number: 29841-69-8
   
Molecular Formula: C14H16N2
   
Molecular Weight: 212.296
   
MDL Number: MFCD00082751

ee Purity: optical rotation: -96.7° (C = 1% in ethanol)

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011709-250mg
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011709-1g
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011709-5g
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011709-25g
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011709-100g
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Purity:99%
Mp:83-86°
 
Pictograms:
Signal Word:Warning
Hazard Statements:H302, H315, H319, H335
Precautionary Statements:P261, P301 + P312, P302 + P352, P304 + P340, P305 + P351 + P338
SDS: See MSDS
 

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Mainly used as a chiral ligand for synthesis of effective chiral catalysts such as bistriflamide catalyst for the enantioselective Diels-Alder reaction1 and Ruthenium complex catalysts for asymmetric hydrogenation reactions.2 Also used to elucidate the chirality of the commercially available analgesic, ibuprofen by the formation of amide and ammonium salt derivatives.3
1. Org. Synth. 1993, 71, 30.
2. Polyhedron 2007, 26, 329.
3. J. Chem. Educ. 1996, 73, 569.

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