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122400

122400-25g



Cyanogen bromide


CAS Number: 506-68-3
   
Molecular Formula: CBrN
   
Molecular Weight: 105.93
   
MDL Number: MFCD00011597


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122400-25g
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122400-100g
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Purity:97%
Bp:61-62°/760mm
Mp:50-53°
Density:2.015
 
Pictograms:
Signal Word:Danger
Hazard Statements:H301, H314
Precautionary Statements:P280, P310, P301 + P310, P305 + P351 + P338
UN#:UN1889
Packing Group:I
Hazard Class:6.1
, 8

Flash Point:>65°
RTECS:GT2100000
MSDS: See MSDS
 
Excepted Quantities:Forbidden

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A reagent used to immobilize proteins, fragment proteins by cleaving peptide bonds, and synthesize cyanamides and other molecules.1,2,3 Applied in the synthesis of mono- and dialkylcyanamides from primary and secondary amines,4 synthesis of guanidines and hydroxyguanidines,5 preparation of aryl nitriles,6 synthesis of α,β-alkynic nitriles,7 preparation of  phenyl cyanate and 2,7-dihydroxynaphthalene dicyanate from phenol and 2,7-dihydroxynaphthalene respectively.8,9
References:
1.        Anal. Biochem. 2010407, 144
2.        Thieme 200510, 1638.
3.        J. Heterocycl. Chem. 19663, 387.
4.        Bioorg.Med. Chem. Lett. 200515, 1815.
5.        Tetrahedron Lett. 200142, 2455.
6.        Ber. Dtsch. Chem. Ges. 190336, 322.
7.        Synthesis 1976, 448.
8.        Org. Synth. 1990, 435.
9.        Polymer 200344, 7861.

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