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012705

012705-1g



(R,R)-(-)-1,2-Diaminocyclohexane

CAS Number: 20439-47-8
   
Molecular Formula: C6H14N2
   
Molecular Weight: 114.19
   
MDL Number: MFCD00062985

ee Purity: 99%

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012705-5g
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012705-25g
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Purity:97%
Bp:104-110°
Mp:40-43°
 
Pictograms:
Signal Word:Danger
Hazard Statements:H314, H318
Precautionary Statements:P280, P301 + P330 + P331, P302 + P352, P304 + P340, P305 + P351 + P338, P310
UN#:UN3259
Packing Group:III
Hazard Class:8
Flash Point:70°
SDS: See MSDS
 
Limited Quantities:5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

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Versatile ligand for the formation of metal complexes.1,2 the (R,R) isomer is generally more active than the (S,S) isomer.3 Used for  Reactions with  Ph(chloromethyl) (isothiocyanato) thiophosphonate and Ph(chloromethyl)(isocyanato)phosphonate,4 synthesis of a new chiral diaminophosphino(silyl)carbene,5 formation of metal complexes of biologically important ligands,6 and synthesis of chiral bifunctional thiourea organocatalysts for stereoselective nucleophilic addition to imines.7 

1. Dalton Trans. 2004, 1563.
2. Zeitschrift fuer Anorganische und Allgemeine Chemie 2008, 634, 2655.
3. Can. J. Chem. 1993, 71, 2102.
4. Russ. J. Gen. Chem. 2008, 78, 2403.
5. Tetrahedron: Asymmetry 2008, 19, 2353.
6. Zeitschrift fuer Naturforschung, B 2008, 63, 1252.
7. Tetrahedron: Asymmetry 2008, 19, 2258.

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