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012706

012706-1g



(S,S)-(+)-1,2-Diaminocyclohexane


CAS Number: 21436-03-3
   
Molecular Formula: C6H14N2
   
Molecular Weight: 114.19
   
MDL Number: MFCD00062986


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012706-1g
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012706-5g
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012706-25g
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012706-100g
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Purity:98%
Bp:104-110°/40mm
Mp:40-43°
 
Pictograms:
Signal Word:Danger
Hazard Statements:H314, H318
Precautionary Statements:P280, P301 + P330 + P331, P302 + P352, P304 + P340, P305 + P351 + P338, P310
UN#:UN2735
Packing Group:II
Hazard Class:8
Flash Point:70°
SDS: See MSDS
 
Limited Quantities:1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

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Versatile ligand for the formation of metal complexes.1 Used in the synthesis of chiral tropocoronands which have potential utility in asymmetric catalysis,2 as a novel organocatalyst for asymmetric vinylogous Michael addition reactions of γ-butenolides to chalcones,3,4  synthesis of tetradentate chiral Schiff base ligand (1Z,1'Z,3E,3'E)-1,1'-diphenyl-3,3'-[(1S,2S)-cyclohexane-1,2-diyldinitrilo]dibut-1-en-1-ol,5 preparation of an HPLC chiral stationary phase (CSP) which has only two ureide functional groups,6 and synthesis of  three-dimensional and chiral one-dimensional CuIICrIII coordination polymers exhibiting ferromagnetism.7  

1. React. Kinet. Catal. Lett. 2009, 96, 175.
2. Tetrahedron Lett. 1997, 38, 7341.
3. Chem. Commun. 2010, 46, 2124.
4. Chem. Commun. 2010, 46, 1751.
5. Acta Crystallogr., Sect. E: Struct. Rep. Online 2008, E64, o1121.
6. Bull. Korean Chem. Soc. 2007, 28, 1980.
7. Inorg. Chem. 2008, 47, 5107.

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