A particularly strong electrophile and versatile triflating reagent in fine chemical and pharmaceutical synthesis.1 Widely used for the synthesis of alkyl and vinyl triflates which are particularly useful in palladium-catalyzed coupling with organotin compounds.2 Applied in the generation of glycosyl triflates from thioglycosides by combination with benzenesulfinyl piperidine or S-(4-methoxyphenyl) benzenethiosulfinate,3,4 stereoselective direct glycosylation with anomeric hydroxy sugars,5 the large scale production of 1-benzenesulfinyl piperidine and other sulfinamides,6 and the direct a-bromination of various ketones.7 Reacts with magnesium alkoxides,8 1,2,3-triazoles,9 and alkoxybenzenes.10
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- Org. Lett. 2000, 2, 4067.
- J. Am. Chem. Soc. 2008, 130, 8537.
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- Chem. Pharm. Bull. 2000, 48, 1999.
- Can. J. Chem. 1999, 77, 258.
- Russ. J. Org. Chem. 2003, 39, 1517.
- Tetrahedron 1996, 52, 12993.
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