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S17975
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Triisopropylsilane
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| Product Number | Your Price | Order |
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S17975-25g |
$23.00 |
In stock
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S17975-100g |
$72.00 |
In stock
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A reducing reagent that allows for more selective reductions (vs. ethyl) such as β-selective reduction of anomeric C-phenyl ketals.1 Has been used in copper triflate catalyzed reductive etherification of trimethylsilyl ethers 2 and highly diastereoelective preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbene complex.3 A silylating reagent used in selective silylation of primary hydroxy groups in the presence of secondary hydroxy groups.4 Also used as a scavenger and to prevent t-Bu-cations reacting with nucleophilic residues in the peptide.5 1. Tetrahedron: Asymmetry 2003, 14, 3243. 2. Tetrahedron Lett. 2003, 44, 7837. 3. Org. Lett. 2006, 8, 4441. 4. J. Organomet. Chem. 1985, 282, 155. 5. Anal. Chem. 2010, 82, 672. |
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