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010818
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4,4,5,5-Tetramethyl-1,3,2-dioxaborolane
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| Product Number | Your Price | Order |
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010818-5g |
$32.00 |
In stock
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010818-25g |
$95.00 |
In stock
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010818-100g |
$235.00 |
In stock
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Also known as pinacolborane. Applied for borylation of aryl chlorides, aryl bromide and aryl iodides in Palladium- or nickel-catalyzed coupling reaction or CuI-catalyzed coupling reaction. 1,2,3,4,5 Used as a borylation reagent for preparing 2-borylpyrroles from 2-iodopyrroles via palladium catalysis.5 Reagent for hydroboration of terminal and internal aliphatic alkenes in the presence of dppm and [Ir(cod)Cl]2,6 for efficient amide-directed catalytic asymmetric hydroboration 7 and for the preparation of boronates for Suzuki-type couplings.8 Recently used for preparing a Boron-substituted analogue of the Shvo hydrogenation catalyst for catalytic hydroboration of aldehydes, imines, and ketones.9 1. Heterocycles 2010, 80, 213. 2. Org. Lett. 2006, 8, 261. 3. Synlett 2006, 1867. 4. Org. Biomol. Chem. 2003, 1, 3724. 5. Tetrahedron Lett. 2006, 47, 7451. 6. Tetrahedron 2004, 60, 10695. 7. J. Am. Chem. Soc. 2008, 130, 3734. 8. Tetrahedron 2004, 60, 5357. 9. Organometallics 2009, 28, 2085. |
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