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S03130

S03130-1g



Bromotrimethylsilane


CAS Number: 2857-97-8
   
Molecular Formula: C3H9BrSi
   
Molecular Weight: 153.10
   
MDL Number: MFCD00000048


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S03130-1g
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S03130-5g
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S03130-10g
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S03130-25g
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S03130-100g
Regular Price: $55.00
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S03130-500g
Regular Price: $215.00
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Purity:95%
Bp:79°
Density:1.188
Refractive Index:1.4232
 
Pictograms:
Signal Word:Danger
Hazard Statements:H226, H314, H318
Precautionary Statements:P280, P301 + P330 + P331, P302 + P352, P304 + P340, P305 + P351 + P338, P310
UN#:UN2924
Packing Group:II
Hazard Class:3
, 8

Flash Point:32°
SDS: See MSDS
 
Limited Quantities:1.0 L (0.3 gallon) (liquid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

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A powerful silylating agent.1,2  An effectively selective reagent for the debenzylation of dibenzyl arylphosphate esters to give the corresponding arylphosphate acids without affecting other functional groups and for P–O silyldealkylation of mixed carboxylate–phosphonate alkyl esters.3,4A reagent well suited for peptide resin deprotection and cleavage.5 Also used for elaboration of aldehydes/ ketones into homologous alpha-beta-unsaturated esters via beta-hydroxy esters.6
1. Silylating Agents, 2nd ed. 1995.
2. Org. Lett.2006, 8, 2007.
3. Synth. Commun.  1992, 22, 923.
4. Chem. Commun. 1979, 739.
5. Peptide Res. 1996, 9, 218.
6. Synth. Commun.  2005, 35, 379.

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