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035787

035787-1g



Tris(Dibenzylideneacetone)dipalladium (0)


CAS Number: 51364-51-3
   
Molecular Formula: C51H42O3Pd2
   
Molecular Weight: 915.70
   
MDL Number: MFCD00013310


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035787-1g
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035787-5g
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035787-25g
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Purity:97%
Mp:152-155°
 
Pictograms:
Signal Word:Warning
Hazard Statements:H302, H315, H319, H335
Precautionary Statements:P261, P301 + P312, P302 + P352, P304 + P340, P305 + P351 + P338
SDS: See MSDS
 

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An organometallic catalyst. Examples of reactions using this reagent are the Negishi coupling, Carroll rearrangement and Trost asymmetric allylic alkylation.1,2 Has been used for for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes,3 the carbonylation of β,β-imidoyl iodides to the corresponding imidate esters,4 Suzuki polycondensation reactions 5 and palladium-mediated cross-coupling reactions.6 Recently used as a effective N-Myristoyltransferase-1 Inhibitor against Melanoma growth In vitro and In vivo.7

1. Eur. J. Inorg. Chem. 2004, 6, 1262.
2. Eur. J. Org. Chem. 2004, 10, 2214.
3. Chem. Eur. J. 2006, 12, 5657.
4. Org. Lett. 2006, 8, 4129.
5. Macromolecules 2009, 42, 8611.
6. Synthesis 2008, 978.
7. Clin. Cancer Res. 2008, 14, 5743.

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