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Purity: | 99.5% |
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Bp: | 81-83° |
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Density: | 1.677 |
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Refractive Index: | 1.321 |
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Pictograms:
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Signal Word: | Danger |
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Hazard Statements: | H302, H314, H318 |
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Precautionary Statements: | P280, P301 + P312, P301 + P330 + P331, P303 + P361 + P353, P304 + P340, P305 + P351 + P338, P310 |
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UN#: | UN3265 |
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Packing Group: | II |
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Hazard Class: | 8
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Risk Statements: | 14-34 |
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Safety Statements: | 25-26-36/37/39-45 |
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SDS: | See MSDS
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Limited Quantities: | 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid) |
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Excepted Quantities: | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) |
A particularly strong electrophile and versatile triflating reagent in fine chemical and pharmaceutical synthesis.1 Widely used for the synthesis of alkyl and vinyl triflates which are particularly useful in palladium-catalyzed coupling with organotin compounds.2 Applied in the generation of glycosyl triflates from thioglycosides by combination with benzenesulfinyl piperidine or S-(4-methoxyphenyl) benzenethiosulfinate,3,4 stereoselective direct glycosylation with anomeric hydroxy sugars,5 the large scale production of 1-benzenesulfinyl piperidine and other sulfinamides,6 and the direct a-bromination of various ketones.7 Reacts with magnesium alkoxides,8 1,2,3-triazoles,9 and alkoxybenzenes.10
- Chim. Oggi 2004, 22, 48.
- Synthesis 1993, 735.
- J. Am. Chem. Soc. 2001, 123, 9015.
- Org. Lett. 2000, 2, 4067.
- J. Am. Chem. Soc. 2008, 130, 8537.
- J. Carbohydr. Chem. 2005, 24, 415.
- Chem. Pharm. Bull. 2000, 48, 1999.
- Can. J. Chem. 1999, 77, 258.
- Russ. J. Org. Chem. 2003, 39, 1517.
- Tetrahedron 1996, 52, 12993.
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