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044829

044829-1ml



Isopropyl magnesium chloride 2M in THF


CAS Number: 1068-55-9
   
Molecular Formula: C3H7MgCl
   
Molecular Weight: 102.85
   
MDL Number: MFCD00000466

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044829-1ml
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044829-10ml
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044829-25ml
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044829-100ml
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044829-800ml
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044829-2.4L
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Density:0.975
 
Pictograms:
Signal Word:Danger
Hazard Statements:H225, H261.2, H314, H318, H335, H351
Precautionary Statements:P210, P223, P301 + P330 + P331, P303 + P361 + P353, P304 + P340, P305 + P351 + P338, P308 + P313
UN#:UN3399
Packing Group:II
Hazard Class:4.3
, 3

Flash Point:-17°
SDS: See MSDS
 
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

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A non-nucleophilic Grignard reagent used primarily to add an iso-propyl group to carbonyl groups,1,2 and as a strong base in aprotic solvents.3 An excellent reagent system for non-cryogenic Grignard formation from aryl bromides and iodides bearing sensitive functional groups when combined with the tridentate ligand bis[2-(N,Ndimethylamino) ethyl] ether.4,5,6 Employed in activation of the amine before addition of the ester,7 and synthesis of 3-oxa- and 3-azabicyclo[3.1.0]hexanes from α,β-unsaturated esters.8 

References

1.        J.Am.Chem.Soc. 196789, 1964. 
2.        Synthesis 1977, 18. 
3.        Pure Appl. Chem. 1980, 21.
4.        Org. Lett. 20068, 305
5.        Org. Lett20068, 3141.
6.        Org. Lett. 20057, 5593.
7.        J. Prakt. Chem. 1997339, 517.
8.        Tetrahedron Lett. 201051, 1955.

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