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128900

128900-5g



N,N'-Dicyclohexylcarbodiimide

CAS Number: 538-75-0
   
Molecular Formula: C13H22N2
   
Molecular Weight: 206.33
   
MDL Number: MFCD00011659


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Purity:99%
Bp:122-124°/6mm
Mp:33-35°
 
Pictograms:
Signal Word:Danger
Hazard Statements:H302, H310, H314, H317, H330
Precautionary Statements:P260, P280, P284, P301 + P312, P302 + P352, P305 + P351 + P338, P310, P333 + P313, P362
UN#:UN2811
Packing Group:III
Hazard Class:6.1
Flash Point:113°
RTECS:FF2160000
SDS: See MSDS
 
Limited Quantities:5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

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Abbrevated as DCC. HOBt or HOAt was proposed as an additive to DCC to reduce racemization.1 Widely used as dehydrating and oxidizing agents for the synthesis such as proteins, amides and esters.2,3,4,5 One of the simplest, mildest and most effective reagents for the preparation of symmetrical anhydrides.6 A combination of DCC and dimethyl sulfoxide is used as a mild oxidizing agent for gentle oxidation of primary alcohols to aldehydes and secondary alcohols to ketones.

  1. Chim. Oggi 2003, 6.
  2. Synlett 2007, 2306.
  3. Biochem. J. 2004, 381, 79.
  4. Tetrahedron 2004, 60, 2447.
  5. Eur. J. Sci. Res. 2009, 31, 510.
  6. J. Org. Chem. 2002, 67, 5226.
  7. Bioorg. Med. Chem. 2006, 14, 4341.

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