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S17975

S17975-5g



Triisopropylsilane


CAS Number: 6485-79-6
   
Molecular Formula: C9H22Si
   
Molecular Weight: 158.36
   
MDL Number: MFCD00009657


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S17975-5g
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S17975-10g
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S17975-25g
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S17975-50g
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S17975-100g
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Purity:98%
Bp:169-170°
Density:0.7726
Refractive Index:1.4358
 
Pictograms:
Signal Word:Warning
Hazard Statements:H226, H315, H319, H335
Precautionary Statements:P210, P280, P305 + P351 + P338
UN#:UN1993
Packing Group:III
Hazard Class:3
Flash Point:37°
SDS: See MSDS
 
Limited Quantities:5.0 L (1.3 gallons) (liquid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

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A reducing reagent that allows for more selective reductions (vs. ethyl) such as β-selective reduction of anomeric C-phenyl ketals.1  Has been used in copper triflate catalyzed reductive etherification of trimethylsilyl ethers 2 and highly diastereoelective preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbene complex.3 A silylating reagent used in selective silylation of primary hydroxy groups in the presence of secondary hydroxy groups.4 Also used as a scavenger and to prevent t-Bu-cations reacting with nucleophilic residues in the peptide.5

1. Tetrahedron: Asymmetry 2003, 14, 3243.
2. Tetrahedron Lett. 2003, 44, 7837.
3. Org. Lett. 2006, 8, 4441.
4. J. Organomet. Chem. 1985, 282, 155.
5. Anal. Chem. 2010, 82, 672.

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