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024773

024773-1g



N-Phenyl bis-trifluoromethane sulfonimide


CAS Number: 37595-74-7
   
Molecular Formula: C8H5F6NO4S2
   
Molecular Weight: 357.25
   
MDL Number: MFCD00000404


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024773-1g
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024773-5g
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024773-25g
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024773-100g
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024773-250g
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024773-500g
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024773-1Kg
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Purity:99%
Mp:100-102°
 
Pictograms:
Signal Word:Warning
Hazard Statements:H302, H315, H319, H335
Precautionary Statements:P261, P301 + P312, P302 + P352, P304 + P340, P305 + P351 + P338
SDS: See MSDS
 

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A mild triflating reagent, useful for the triflation of phenols and amines (especially aliphatic secondary amines; aromatic secondary amines do not react),1,2,3 for the preparation of triflones,4 and for the preparation of enol triflates from carbonyl compounds.5 Recently applied as testing reagent in new amination of alcohols using α-hydroxy esters as substrates 6 and for preparation of 4-deoxy-ε-rhodomycinone from rhodomycinone via triflation.7

Reference
1.        J. Am. Chem. Soc. 1990112, 8578.
2.        Tetrahedron 199147, 3485.
3.        Org. Lett. 20024, 1231.
4.        Org. Chem. 199742, 3875.
5.        Acc. Chem. Res. 198821, 47.
6.        Synlett 2002, 0528.
7.        FR 2871156 A1 200512092005.



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