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005027

005027-1g



N,N-Diisopropylethylamine


CAS Number: 7087-68-5
   
Molecular Formula: C8H19N
   
Molecular Weight: 129.25
   
MDL Number: MFCD00008868


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005027-1g
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005027-5g
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005027-25g
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005027-100g
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005027-500g
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005027-1L
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005027-2.5L
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005027-4L
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005027-18L
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Purity:99%
Bp:127°
Density:0.742
Refractive Index:1.414
 
Pictograms:
Signal Word:Danger
Hazard Statements:H226, H314, H318
Precautionary Statements:P201, P261, P280, P301 + P310, P301 + P330 + P331, P302 + P350, P304 + P340, P305 + P351 + P338, P310
UN#:UN2733
Packing Group:II
Hazard Class:3
, 8

Flash Point:12°
SDS: See MSDS
 
Limited Quantities:1.0 L (0.3 gallon) (liquid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

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N,N'-Diisopropylethylamine is also called Hünig's base or DIPEA. A good base but a poor nucleophile. Use as a selective reagent in the acylation and  alkylation of secondary amines to tertiary amines by alkyl halides.1 A peptide synthesis reagent.2,3 Also used in synthesis of sscorpionine (a complex heterocyclic compound) by a reaction with disulfur dichloride catalyzed by DABCO in a remarkable one-pot synthesis.4
  1. Arkivoc (EJ-1549C) 2005, 287. 
  2. Fmoc Solid Phase Peptide Synthesis: A Practical Approach, Oxford University Press. 2000
  3. Org. Lett2000, 2, 2439.
  4. Angew. Chem. Int. Ed. 1997, 36, 281.

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