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005419

005419-5g



Triisopropyl borate


CAS Number: 5419-55-6
   
Molecular Formula: C9H21BO3
   
Molecular Weight: 188.08
   
MDL Number: MFCD00008872


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005419-5g
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005419-25g
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005419-100g
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005419-500g
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005419-2.5L
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005419-4L
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Purity:99%
Bp:139-141°
Density:0.815
Refractive Index:1.376
 
Pictograms:
Signal Word:Danger
Hazard Statements:H225, H303, H320, EUH018
Precautionary Statements:P210, P303 + P361 + P353, P305 + P351 + P338, P403 + P235
UN#:UN2616
Packing Group:II
Hazard Class:3
Flash Point:17°
RTECS:ED5950000
SDS: See MSDS
 
Limited Quantities:1.0 L (0.3 gallon) (liquid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

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A catalyst for the production of resins, waxes, paints and varnishes and a precursor of borate esters which are used in the Suzuki coupling reaction.1,2 Also used in polymer additives.3 Triisopropyl borate, instead of trimethyl borate, is shown to be the best of available alkyl borates to avoid contamination of small mounts of the opposite stereoisomers, bis-alkylation leading to the borinic acid derivatives and the formation of trialkylboranes in the classical synthesis of aryl- and 1-alkenylboronic acids or their esters from Grignard reagents or lithium reagents and trialkyl borates. 4,5,6

  1. Synth. Commun. 2005, 35, 2005.
  2. From bench to market: the evolution of chemical synthesis. Oxford university press. 2000, 134.
  3. Liq. Cryst. 2005, 32, 921.
  4. Chim. Oggi 2003, 21, 70.
  5. Chem. Rev. 1995, 95, 2457.
  6. Org. Lett. 2006, 8, 2031.

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