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034279

034279-1g



Palladium (0) tetrakis(triphenylphosphine)


CAS Number: 14221-01-3
   
Molecular Formula: C72H60P4Pd
   
Molecular Weight: 1155.58
   
MDL Number: MFCD00010012


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034279-1g
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034279-5g
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034279-25g
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Purity:98%
Mp:100-105°
 
Pictograms:
Signal Word:Warning
Hazard Statements:H302, H315, H319, H335
Precautionary Statements:P261, P305 + P351 + P338
Risk Statements:36/37/38
Safety Statements:22-24/25-26-28-36/37/39
SDS: See MSDS
 

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A catalyst for coupling reactions such as the Heck, Suzuki, Negishi and Sonogashira cross-coupling reactions and Buckwald-Hartwig aminations.1,2,3,4,5 High yielding palladium-catalyzed reductive debromination of fused diporphyrins.A catalyst employed in arylation of sulfonamide stabilised enolates7 and allylation of Meldrum's acids by allylic alcohols without prior activation of allylic hydroxy group.8

1. Tetrahedron Lett. 1993, 34, 2813.
2. J. Phys. Chem. C2008, 112, 10273.
3. Adv. Synth. Catal. 2009, 351, 1727.
4. Synthesis 2007, 1061
5. Platinum Met. Rev. 2010, 54, 69.
6. Org. Lett. 2006, 8, 4141.
7. Tetrahedron Lett. 2005, 46, 1597.
8. Heterocycles 2005, 65,1917.

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