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035595

035595-1g



1,1-Thiocarbonyldiimidazole


CAS Number: 6160-65-2
   
Molecular Formula: C7H6N4S
   
Molecular Weight: 178.22
   
MDL Number: MFCD00005289


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035595-1g
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035595-5g
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035595-10g
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035595-25g
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035595-100g
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Purity:90%
Mp:98-100°
 
Pictograms:
Signal Word:Warning
Hazard Statements:H302, H315, H319, H335
Precautionary Statements:P261, P301 + P312, P302 + P352, P304 + P340, P305 + P351 + P338
SDS: See MSDS
 

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A useful reagent in biochemical synthesis. Used in the deoxygenation of alcohols with tributyltin hydride and diols with lithium aluminum hydride,1 synthesis of monoglycosyl imidazoles and 1,1′-di-O-glycosides by direct glycosylation process from reducing sugar,2 ring closure reaction of o-aminoarylsulfonamides3 and cyclic thiocarbonylation of N,N-disubstituted-aminocarbohydroxamic acids.4 Also used for corrosion inhibition on mild steel in H2SO4 solution.5

1.  J. Org. Chem. 2007, 72, 5276.
2. Tetrahedron Lett. 2002, 43, 241.
3. Tetrahedron 1998, 54, 4935.
4. Z. Naturforsch. 2006, 61b, 83.
5. Acta Phys. Chim. Sin. 2008, 24, 1185.

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