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001061

001061-5g



Sodium chlorodifluoroacetate


CAS Number: 1895-39-2
   
Molecular Formula: C2ClF2NaO2
   
Molecular Weight: 152.46
   
MDL Number: MFCD00064771


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001061-5g
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001061-25g
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001061-100g
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001061-500g
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Purity:96%
Mp:196-198°
 
Pictograms:
Signal Word:Warning
Hazard Statements:H302, H315, H319, H335
Precautionary Statements:P261, P301 + P312, P302 + P352, P304 + P340, P305 + P351 + P338
Risk Statements:36/37/38
Safety Statements:26-37/39
SDS: See MSDS
 

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Sodium chlorodifluoroacetate is an environmentally benign difluorocarbene precursor used for: Synthesis of 1,3-difluoroaromatics,1 Esterification of chlorodifluoroacetic acid with polyfluoro and hydrocarbon alcohols,2 Synthesis of chlorohydrins from glycidyl ethers by difluorocarbene-induced facile regioselective ring opening,3 Wittig reaction of 3- and 8-formyl deuteroporphyrin dimethyl esters (1 or 2) with triphenylphosphonium difluoromethylide,4  and Synthesis of Geminal difluorinated cyclopropanes.5 

Recently applied to functionalization of ethylene-propylene-diene rubber (EPDM).6

1. Org. Lett., 2002, 4, 3871.
2. J. Fluorine Chem. 2002, 113, 47.
3. Can. J. Chem. 2004, 82, 1249.
4. Heterocycles 2000, 52, 383.
5. Z. Naturforsch. 2003, 58b, 997.
6. React. Funct. Polym. 2005, 64, 151.

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