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009411

009411-1g



Triisopropylsilyl trifluoromethanesulfonate


CAS Number: 80522-42-5
   
Molecular Formula: C10H21F3O3SSi
   
Molecular Weight: 306.42
   
MDL Number: MFCD00009913


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009411-1g
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009411-5g
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009411-10g
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009411-25g
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009411-100g
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009411-1Kg
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Purity:98%
Bp:45°/0.03mm
Density:1.140
 
Pictograms:
Signal Word:Danger
Hazard Statements:H314, H318
Precautionary Statements:P280, P310, P305 + P351 + P338
UN#:UN3265
Packing Group:II
Hazard Class:8
Flash Point:100°
SDS: See MSDS
 
Limited Quantities:1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

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Highly reactive silylating agent and Lewis acid capable of converting primary and secondary alcohols to the corresponding triisopropylsilyl ethers 1 and converting ketones and lactones into their enol silyl ethers;2 protection of terminal alkynes;3 promoting conjugate addition of alkynylzinc compounds to αβ-enones;3 preparation of (triisopropylsilyl)diazomethane.3 

1. Synthesis 2004, 2062.  
2. Org. Lett.2005, 7, 1415.
3. Encyclopedia of Reagents for Organic Synthesis.  John Wiley & Sons, 2007.

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