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011708

011708-250mg



(1R,2R)-(+)-1,2-Diphenylethylenediamine


CAS Number: 35132-20-8
   
Molecular Formula: C14H16N2
   
Molecular Weight: 212.30
   
MDL Number: MFCD00082769

ee Purity: +97.7°(C=1% in ethanol)

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011708-250mg
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011708-1g
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011708-5g
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011708-25g
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Purity:99%
Mp:79-81°
 
Pictograms:
Signal Word:Warning
Hazard Statements:H302, H315, H319, H335
Precautionary Statements:P261, P301 + P312, P302 + P352, P304 + P340, P305 + P351 + P338
SDS: See MSDS
 

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A chiral building block for preparation of chiral stationary phases with strong enantioseparation ability. 1,2,3 One of the most important chiral ligand for synthesis of chiral complex as highly efficient catalysts such as chiral Ti(IV) complex for highly enantioselective silylcyanation of aliphatic and aromatic aldehydes,4 polymer-supported chiral 1,2-diphenylethylenediamine for asymmetric hydrogenation of ketone,5 3-Cu(OAc)2 complex for the Henry reaction6 and chiral macrocyclic lanthanide complexes.7 Also used for synthesis of optically active polyamides.8

1. Chromatographia 2006, 64, 641.
2. J. Liq. Chromatogr. Related Technol. 2010, 33, 46.
3. Chirality 2009, 22, 604.
4. Chem. Commun. 2002, 54.
5. Org. Lett. 2003, 5, 4559.
6. Org. Lett.2007, 9, 3595.
7. Polyhedron 2003, 22, 2877.
8. Bull. Chem. Soc. Jpn. 1986, 59, 931.

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